; ; ; "ActiveFedora::Aggregation::ListSource" . a , ; "Synthesis and photochemistry of 2-phenylthiazole"; "depositor@wpi.edu"; "Pavlik, James W."; "Asting, Elizabeth M."; "2-phenylthiazole was synthesized from bromoacetaldehyde diethyl acetal and thiobenzamide. The photochemistry of 2-phenylthiazole was studied upon irradiation at 254nm and with light of wavelenghth >290nm in methanol, acetonitrile, and hexane solvents. In addition to the previously observed phototransposition to yield 3-phenylisothiazole, 4-phenylthiazole, and 5-phenylisothiazole, 2-phenylthiazole was observed to undergo photofragmentation to yield benzonitrile. The yield of benzonitrile was highest (2%) upon irradiation in methanol at 254nm and lowest upon irradiation in acetonitrile at >290nm. The yields of the phototransposition products was also found to depend on the wavelength of light used for irradiation. When >290nm light was used, the amount of 4-phenylthiazole produced increased, while the amounts of the other phototransposition products decreased. 5-Deuterio-2-phenylthiazole was also synthesized and its photochemistry studied to further examine the phototransposition mechanism of 2-phenylthiazole. 5-Deuterio-2-phenylthiazole was irradiated in acetonitrile and with light 254nm to maximize the yield of the 3-phenylisothiazole phototransposition product. This product was isolated, and the location of the deuterium examined."; "Worcester Polytechnic Institute"; "2000-01-01"; "2000"; "2021-09-16T21:34:22.453459527-04:00"^^; "00D050M"; ; "Major Qualifying Project"; "Chemistry"; ; ; "http://rightsstatements.org/vocab/InC/1.0/"; ; ; "This report represents the work of one or more WPI undergraduate students submitted to the faculty as evidence of completion of a degree requirement. WPI routinely publishes these reports on its website without editorial or peer review."; ; "StudentWork" . ; .